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Graphite formation begins with the burial of organic-rich sediments in ancient seabeds and lake basins. Over tens to hundreds of millions of years, increasing pressure and temperature (typically >300 °C and >3 kbar) induce metamorphism, reorganizing carbon atoms into planar, hexagonal layers.
Metamorphic Grade: Higher temperature and pressure yield larger flake sizes and purer crystalline structures.
Host Rocks: Graphite typically occurs in schists, gneisses, and marble zones where organic material was abundant.
At the atomic level, graphite consists of sp²‑bonded carbon atoms arranged in hexagonal sheets. These layers stack via weak van der Waals forces, allowing easy interlayer sliding.
Hexagonal Arrangement: Each carbon atom bonds to three neighbors, forming two‑dimensional graphene planes.
Layer Spacing: Approximately 0.335 nm between planes—a key factor in lubrication and intercalation applications.
Graphite’s in‑plane (parallel to layers) conductivity is up to 10,000 S/cm, while cross‑plane conductivity is orders of magnitude lower. This anisotropy makes graphite ideal for electrodes, brushes, and conductive coatings.
Weak interlayer forces enable easy shear between sheets under load, providing dry‑film lubrication in bearings, seals, and high‑temperature environments.
With in‑plane thermal conductivity exceeding 2000 W/m·K, graphite effectively dissipates heat in electronics, heat spreaders, and thermal interface materials.
Graphite resists oxidation up to 600 °C in air (and above 3000 °C in inert atmospheres), and remains inert to most acids and alkalis—crucial for corrosive or high‑temperature processing.
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Electronics & Energy Storage: Anode material in lithium‑ion batteries, conductive additives in fuel cells and supercapacitors.
Metallurgy & Foundry: Refractory linings, crucibles, and coatings that endure thermal shock.
Lubrication & Sealing: Dry‑film lubricants, high‑temperature gaskets, and seals in aerospace and automotive sectors.
Thermal Management: Heat spreaders, thermal interface pads, and composite heat sinks for LEDs and power electronics.
The millions‑of‑years metamorphic transformation of organic matter into crystalline graphite has yielded a material with unparalleled layered architecture and multifunctional properties. From anisotropic conductivity to robust chemical resistance, natural graphite remains indispensable across advanced industrial sectors.
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